| 11 | 0 | 42 |
| 下载次数 | 被引频次 | 阅读次数 |
为实现快速监测恶臭污染中的关键物质硫化物与苯系物,研制了基于气相色谱-光离子化(GC-PID)检测技术的便携式分析仪。该仪器集成了采样、分离与检测模块,具备良好便携性,可在10分钟内同步检测硫化氢、甲硫醇、乙苯等9种污染物。各组分线性相关系数大于0.999,方法检出限为0.002~0.04 mg/m3,相对标准偏差为0.23%~3.3%,并能有效识别实际样品中多种共存组分,为恶臭污染现场快速筛查与溯源提供了新的技术路径与分析工具。
Abstract:A portable analyzer based on gas chromatography-photoionization detection was developed for rapid monitoring of key sulfur compounds and benzene homologues in odor pollution. The integrated instrument combines sampling, separation, and detection modules, offering high portability. It enables simultaneous detection of nine pollutants, including hydrogen sulfide, methyl mercaptan, and ethylbenzene, within 10 minutes. All compounds show linear correlation coefficients above 0.999, method detection limits of 0.002-0.04 mg/m3, and relative standard deviations of 0.23%-3.3%, with effective identification of multiple coexisting components in real samples. This study provides a reliable analytical tool for rapid on-site screening and source tracing of odor pollution.
[1]李俊成.恶臭物质检测方法与实验研究[D].天津:河北工业大学,2017.
[2]路鹏,苏昭辉,王亘,等.填埋场大气中化合物分析与恶臭指示物筛选[J].环境科学,2011,32(04):936-942.
[3]芦会杰.生活垃圾转运站环境空气中恶臭成分分析及污染评价[J].环境化学,2020,39(11):3111-3119.
[4]王攀,黄燕冰,袁传胜,等.国内成功运营的餐厨垃圾处理厂臭气排放特征研究[J].环境工程学报,2014,8(02):624-630.
[5]任敏,魏竹秋,章嘉晴.气相色谱法测定空气中15种含硫恶臭污染物及其应用[J].当代化工研究,2024(11):53-55.
[6]曲晶明,叶能胜,亓学奎,等.热脱附/气相色谱-质谱法测定环境空气中的挥发性有机物[J].分析仪器,2021(4):58-65.
[7]胡冠九,高占啟,张涛,等.环境空气中异味物质的监测、评价与溯源[J].中国环境监测,2019,35(04):10-19.
[8]于志伟,潘玉珏,王倩,等.傅里叶红外光谱技术在恶臭气体检测中的应用[J].中国仪器仪表,2019(02):38-40.
[9]李金旭,侯可勇,赵无垛,等.磁增强光电子电离便携式飞行时间质谱仪的研制及其在挥发性还原态硫化物测量中的应用[J].分析化学,2015,43(03):444-450.
[10]朱海俭,黄学敏,曹利,等.预浓缩与GC-MS联用分析垃圾填埋场恶臭气体[J].中国环境监测,2012,28(04):91-94.
[11]张凤菊,金玲仁,李红莉,等.气质联用法测定环境空气中有机硫化物[J].环境监测管理与技术,2014,26(03):44-47.
[12]张驭风,魏庆农,张伟.用于挥发性有机化合物总量检测的光离子化检测器电离室的设计[J].分析仪器,2006(2):13-17.
[13]You D,Seon Y,Jang Y,et al.A portable gas chromatograph for real-time monitoring of aromatic volatile organic compounds in air samples[J].Journal of Chromatography A,2020,1625(prepublish):461267.
[14]Isix F,Alondra M,Hugh G,et al.Characterizing the performance of a compact BTEX GC-PID for Near-Real time analysis and field deployment[J].Sensors,2021,21(6):2095-2095.
[15]Nasreddine R,Person V,Serra A C,et al.Development of a novel portable miniaturized GC for near real-time low level detection of BTEX[J].Sensors&Actuators:B.Chemical,2016,224,159-169.
[16]Pang X B,Nan H J,Zhong J P,et al.Low-cost photoionization sensors as detectors in GC×GC systems designed for ambient VOC measurements[J].Science of the Total Environment,2019,664,771-779.
基本信息:
中图分类号:TH833;O657;X831
引用信息:
[1]陈晨,孙风界,曹春兰,等.GC-PID便携式气相色谱仪的研制及在硫化物与苯类恶臭气体快速筛查中的应用[J].分析仪器,2026,No.266(03):17-23.
2026-05-28
2026-05-28